Cu2ZnSnS4 absorber layers obtained through sulphurization of metallic precursors: Graphite box versus sulphur flux

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Cu2ZnSnS4 absorption layers with controlled phase purity

We report the synthesis and characterization of Cu2ZnSnS4 (CZTS) with controlled phase purity. The precursor was first prepared using sequential electrodeposition of Cu, Zn, and Sn in different orders. The Cu/(Sn+Zn) ratio in each stacking order was also varied. The precursor was subjected to annealing at 200°C and sulfurization at 500°C in a 5%-H2S/Ar atmosphere for the formation of CZTS. The ...

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ژورنال

عنوان ژورنال: Thin Solid Films

سال: 2013

ISSN: 0040-6090

DOI: 10.1016/j.tsf.2012.11.080